The following post is courtesy of Pamela Murray, an MSc Conservation Practice Student at Cardiff University and conservation volunteer at Glamorgan Archives. She has been working on the Edward Thomas Conservation project as a student conservator thanks to the generous support of the National Manuscript Conservation Trust.
Dating back to the 1st century AD and used all the way until the 19th century, iron gall ink was a common writing ink throughout Europe. It is made from iron sulphates, gum, tannins extracted from galls (generally oak tree galls), and water. There are different recipes and methods found throughout history to make iron gall ink, and some even include using wine.
So, one of the problems with this historic ink is that the degradation process of it can be detrimental to the paper or work of art it has been used for.
Excess iron sulphates Fe(II) accelerate the oxidation process in the paper or parchment due to their reaction with atmospheric oxygen. There are three signs of degradation:
- Halo-ing: when there is a faint spreading of the ink.
- Burnthrough: when the ink becomes increasingly visible on the reverse of the page.
- Lacing: where the inked area is so weak and friable that it causes the paper to cracks and eventually fall out. this is possibly the most detrimental.
Luckily, none of the manuscripts from the Edward Thomas archive had lacing. They did, however, have a slight haloing. In order to test the paper for iron gall ink, we dipped an indicator paper impregnated with bathophenanthroleine is dipped in deionised water and spot tested on an appropriate area. The bathophenanthroleine reacts with ferrous ions to form a pink complex.
Many of the Edward Thomas notebooks tested positive for iron gall ink, meaning that none of the papers can be treated with water because the ferrous ions could spread, causing further degradation. Luckily for us, in a paper written in 1995, Neeval suggested a calcium phytate aquaeous treatment, where the phytate chellates the iron (II) ions. It does not break down Iron (III) because it is a stable molecule, so that means the ink doesn’t fade. However, this treatment strategy has been met with some challenges because it is highly interventive, and there have been many international projects looking into the treatment of iron gall ink with calcium phytate. (Kolar et al. 2005, Kolbe 2004, Tse et al., 2005, Zappala and De Stefani 2005, Botti et al. 2005, Hofmann et al. 2004, Jembrih-Simbürger et al. 2004, Reissland and de Groot 1999.)
Looking at the altenatives, this is the most effective aqueous method of prolonging iron gall ink’s life time with minimal side effects. So, it was agreed that treating the notebooks in question with a calcium phytate bath was the best step forward to prevent further damage due to iron gall ink.
It is with thanks to the National Manuscript Conservation Trust and the Glamorgan Archives that the Edward Thomas manuscripts housed at Cardiff University’s Special Collections and Archives could be treated and conserved accordingly. In the same breath, it has served as an important learning tool for myself as a conservation student.
The BBC has a great clip about iron gall ink: http://www.bbc.co.uk/programmes/p033dbrb in BBC Four’s documentary Oak Tree: Nature’s Greatest Survivor. The full programme can be purchased from the BBC Store.
Neevel, J. (2009). Application Issues of the Bathophenanthroline Test for Iron(II) Ions. Restaurator 30, pp.3–15.